NILE CHEMICALS
Material
Safety Data Sheet
Tin(II)
sulfate
Section
1 - Chemical Product and Company Identification |
MSDS Name:
Tin(II) sulfate
Synonyms: Stannous sulfate.
Company Identification:
Section
2 - Composition, Information on Ingredients |
|||||
|
CAS# |
Chemical
Name |
Percent |
EINECS/ELINCS |
|
|
7488-55-3 |
Tin(II)
sulfate |
95
|
231-302-2 |
|
Section
3 - Hazards Identification |
|||||
Potential Health Effects
Eye: Causes eye
irritation.
Skin: Causes skin
irritation. May be harmful if absorbed through the skin.
Ingestion: May cause
irritation of the digestive tract. May be harmful if swallowed.
Inhalation: Causes
respiratory tract irritation. May be harmful if inhaled.
Chronic: Prolonged or
repeated skin contact may cause dermatitis. Chronic exposure to tin oxide dusts
and fumes may result in stannosis (benign pneumoconiosis).
Section
4 - First Aid Measures |
Eyes: Immediately
flush eyes with plenty of water for at least 15 minutes, occasionally lifting
the upper and lower eyelids. Get medical aid.
Skin: Get medical aid.
Immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes.
Ingestion: Do not
induce vomiting. Get medical aid.
Inhalation: Remove
from exposure and move to fresh air immediately. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section
5 - Fire Fighting Measures |
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand,
MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 1; Instability: 1
Section
6 - Accidental Release Measures |
General Information:
Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum
or sweep up material and place into a suitable disposal container. Avoid
generating dusty conditions. Provide ventilation. Do not let this chemical enter
the environment.
Section
7 - Handling and Storage |
Handling: Use with
adequate ventilation. Minimize dust generation and accumulation. Do not get in
eyes, on skin, or on clothing. Do not ingest or inhale.
Storage: Store in a
cool, dry place. Store in a tightly closed container.
Section
8 - Exposure Controls, Personal Protection |
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash
facility and a safety shower. Use adequate ventilation to keep airborne
concentrations low.
Exposure Limits
Chemical
Name |
ACGIH |
NIOSH |
OSHA
- Final PELs |
Tin(II)
sulfate |
2
mg/m3 TWA (as Sn, except Tin hydride) (listed under Tin inorganic
compounds). |
2
mg/m3 TWA (as Sn, except Tin oxide) (listed under Tin inorganic
compounds). |
2
mg/m3 TWA (as Sn, except oxides) (listed under Tin inorganic compounds). |
OSHA Vacated PELs:
Tin(II) sulfate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate
protective eyeglasses or chemical safety goggles as described by OSHA's eye and
face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate
protective gloves to prevent skin exposure.
Clothing: Wear
appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR
1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN
149 approved respirator if exposure limits are exceeded or if irritation or
other symptoms are experienced.
Section
9 - Physical and Chemical Properties |
Appearance: white - off-white - fine
Odor: none reported
pH: 2.0 (50 g/L aq.sol.)
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not applicable.
Freezing/Melting Point:360 deg C
Decomposition Temperature:378 deg C
Solubility: 330 g/L (20°C)
Specific Gravity/Density:3.95 @ 20C
Molecular Formula:O4SSn
Molecular Weight:214.75
Section
10 - Stability and Reactivity |
Chemical Stability: Moisture sensitive.
Conditions to Avoid: Incompatible materials, dust generation, heating to
decomposition, exposure to moist air or water.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Oxides of sulfur, tin/tin oxides.
Hazardous Polymerization: Will not occur.
Section
11 - Toxicological Information |
RTECS#:
CAS# 7488-55-3: WT1255000
LD50/LC50:
CAS# 7488-55-3:
Oral, mouse: LD50 = 2152 mg/kg;
Oral, rat: LD50 = 2207 mg/kg;
.
Carcinogenicity:
CAS# 7488-55-3: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: Adverse reproductive effects have occurred in
experimental animals.
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:
Section
12 - Ecological Information |
Ecotoxicity: No data available. No information available.
Environmental: No information available.
Physical: No information available.
Other: Do not empty into drains.
Section
13 - Disposal Considerations |
Chemical waste
generators must determine whether a discarded chemical is classified as a
hazardous waste. US EPA guidelines for the classification determination are
listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state
and local hazardous waste regulations to ensure complete and accurate
classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section
14 - Transport Information |
|
US
DOT |
|
Shipping
Name: |
Not
regulated. |
Not
regulated. |
Hazard
Class: |
|
|
UN
Number: |
|
|
Packing
Group: |
|
|
Section
15 - Regulatory Information |
TSCA
CAS# 7488-55-3 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health &
Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a
Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA
Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR
under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7488-55-3: immediate, delayed.
Section 313 No chemicals are reportable
under Section 313.
Clean Air Act:
This material does not contain any hazardous air
pollutants.
This material does not contain any Class 1 Ozone
depletors.
This material does not contain any Class 2 Ozone
depletors.
Clean Water Act:
None of the chemicals in this product are listed
as Hazardous Substances under the CWA.
None of the chemicals in this product are listed
as Priority Pollutants under the CWA.
None of the chemicals in this product are listed
as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are
considered highly hazardous by OSHA.
STATE
CAS# 7488-55-3 can be found on the following state
right to know lists:
California No Significant Risk Level: None of the chemicals in this product are
listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse
immediately with plenty of
water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 7488-55-3: No information available.
CAS# 7488-55-3 is listed on
This product has a WHMIS classification of D2B,
D2A.
This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations and the MSDS contains all of the information
required by those regulations.
Canadian Ingredient Disclosure List
CAS# 7488-55-3 is not listed on the Canadian
Ingredient Disclosure List.
Section
16 - Additional Information |
The information above
is believed to be accurate and represents the best information currently
available to us. However, we make no warranty of merchantability or any other
warranty, express or implied, with respect to such information, and we assume no
liability resulting from its use. Users should make their own investigations to
determine the suitability of the information for their particular purposes. In
no event shall Nile chemicals be liable for any claims, losses, or damages of
any third party or for lost profits or any special, indirect, incidental,
consequential or exemplary damages, howsoever arising, even if Fisher has been
advised of the possibility of such damages.
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