NILE CHEMICALS

Thiosemi carbazide

1. Product Identification

Synonyms: N-Aminothiourea; Thiocarbamylhydrazine; Hydrazinecarbothioamide 
CAS No.: 79-19-6 
Molecular Weight: 91.14 
Chemical Formula: 
CH5N3S


2. Composition/Information on Ingredients

Ingredient                                CAS No         Percent        Hazardous                                 
---------------------------------------   ------------   ------------   ---------  
Hydrazinecarbothioamide                   79-19-6          90 - 100%       NO

3. Hazards Identification

----------------------------------------------------------------------------------------------------------- 
Health Rating: 4 - Extreme (Poison) 
Flammability Rating: 0 - None 
Reactivity Rating: 1 - Slight 
Contact Rating: 3 - Severe (Life) 
Storage Color Code: Blue (Health) 

----------------------------------------------------------------------------------------------------------- 
Potential Health Effects 
---------------------------------- 
Inhalation:  None identified. 
Ingestion: Headache, nausea, vomiting, dizziness, gastrointestinal irritation. 
Skin Contact: Irritation, allergic reaction may develop. 
Eye Contact: Irritation. 
Chronic Exposure: Blood, and liver damage. 
Aggravation of Pre-existing Conditions: No information found.


4. First Aid Measures

Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Prompt action is essential. 
Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention. 
Skin Contact: In case of contact, flush skin with water. 
Eye Contact: In case of eye contact, immediately flush with plenty of water for at least 15 minutes. 


5. Fire Fighting Measures

Fire: Not expected to be a fire hazard. 
Explosion: No information found. 
Fire Extinguishing Media: Use extinguishing media appropriate for surrounding fire. 
Special Information: Firefighters should wear proper protective equipment and self-contained breathing apparatus with full facepiece operated in positive pressure mode.


6. Accidental Release Measures

Wear self-contained breathing apparatus and full protective clothing. With clean shovel, carefully place material into clean, dry container and cover; remove from area. Flush spill area with water.


7. Handling and Storage

Keep container tightly closed. Store in secure poison area. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.


8. Exposure Controls/Personal Protection

Airborne Exposure Limits: None established. 
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. 
Personal Respirators (NIOSH Approved): For conditions of use where exposure to the substance is apparent and engineering controls are not feasble, consult an industrial hygienist. For emergencies, or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres. 
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. 
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area. 


9. Physical and Chemical Properties

Appearance: White Crystal  Powder . 
Odor: Odorless. 
Solubility: Moderate (1-10%) 
Specific Gravity: No information found. 
pH: No information found. 
% Volatiles by volume @ 21C (70F): 0 
Boiling Point: No information found. 
Melting Point: 183C (361F) 
Vapor Density (Air=1): Not applicable. 
Vapor Pressure (mm Hg): Not applicable. 
Evaporation Rate (BuAc=1): No information found. 


10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage. 
Hazardous Decomposition Products: Oxides of nitrogen, oxides of sulfur. 
Hazardous Polymerization:  Will not occur. 
Incompatibilities: No information found. 
Conditions to Avoid:  Heat.


11. Toxicological Information

  --------\Cancer Lists\------------------------------------------------------
                                         ---NTP Carcinogen---
  Ingredient                             Known    Anticipated    IARC Category
  ------------------------------------   -----    -----------    -------------
  Hydrazinecarbothioamide (79-19-6)       No          No            None

12. Ecological Information

Environmental Fate: No information found. 
Environmental Toxicity: No information found.


13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.


14. Transport Information

Not regulated.


15. Regulatory Information

  --------\Chemical Inventory Status - Part 1\---------------------------------
  Ingredient                                       TSCA  EC   Japan  Australia
  -----------------------------------------------  ----  ---  -----  ---------
  Hydrazinecarbothioamide (79-19-6)                 Yes  Yes   Yes      Yes                                     
 
  --------\Chemical Inventory Status - Part 2\---------------------------------
                                                          --Canada--
  Ingredient                                       Korea  DSL   NDSL  Phil.
  -----------------------------------------------  -----  ---   ----  -----
  Hydrazinecarbothioamide (79-19-6)                 Yes   Yes   No     Yes             
 
  --------\Federal, State & International Regulations - Part 1\----------------
                                             -SARA 302-    ------SARA 313------
  Ingredient                                 RQ    TPQ     List  Chemical Catg.
  -----------------------------------------  ---   -----   ----  --------------
  Hydrazinecarbothioamide (79-19-6)          100   100*    Yes        No
 
  --------\Federal, State & International Regulations - Part 2\----------------
                                                        -RCRA-    -TSCA-
  Ingredient                                 CERCLA     261.33     8(d)
  -----------------------------------------  ------     ------    ------
  Hydrazinecarbothioamide (79-19-6)          100        P116       No           
 
 
Chemical Weapons Convention:  No     TSCA 12(b):  No     CDTA:  No
SARA 311/312:  Acute: Yes      Chronic: Yes  Fire: No  Pressure: No
Reactivity: No          (Pure / Solid)

ustralian Hazchem Code: 2XE 
Poison Schedule: None allocated. 
WHMIS: 
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. 

16. Other Information

Disclaimer: Nile Chemicals. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. NILE CHEMICALS. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, NILE CHEMICALS. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.

 

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