NILE CHEMICALS

                                                         SODIUM OXALATE


1. Product Identification

CAS No.: 62-76-0
Molecular Weight: 134.00
Chemical Formula: NaOCOCOONa
Product Codes: 191167


2. Composition/Information on Ingredients

  Ingredient           CAS No         Percent        Hazardous                                  
  -----------------   ------------   ------------    ---------  
  Sodium Oxalate      62-76-0         99 - 100%       Yes                                                                    
 

3. Hazards Identification

Inhalation: Inhalation of dust is corrosive to mucous membranes. Oxalates can be absorbed through the lungs. Symptoms of poisoning include nervousness, cramps, central nervous system depression.
Ingestion: Mean lethal dose for oxalates in adults is estimated at 15-30 grams with death within a few hours or even minutes. Corrosive action on the mucosa and severe gastrointestitis can occur with pain, vomiting, etc. Sharp reduction of serum calcium can cause disfunction of the brain. Calcium oxalate may be deposited in the kidneys.
Skin Contact: Corrosive. Symptoms of redness, pain, and severe burn can occur.
Eye Contact: Corrosive. Contact can cause blurred vision, redness, pain and severe tissue burns.
Chronic Exposure: Circulatory failure or nervous system irregularities may follow prolonged calcium metabolism disturbances due to oxalation.
Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems, or impaired liver, kidney or respiratory function may be more susceptible to the effects of the substance.


4. First Aid Measures

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Ingestion: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.


5. Fire Fighting Measures

Fire: Not considered to be a fire hazard.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.


6. Accidental Release Measures

Ventilate area of leak or spill. Keep unnecessary and unprotected people away from area of spill. Wear appropriate personal protective equipment as specified in Section 8.


7. Handling and Storage

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.


8. Exposure Controls/Personal Protection

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerine, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.


9. Physical and Chemical Properties

Appearance: White powder.
Odor: Odorless.
Solubility: 3.7g/100g water @ 20C (68F).
Specific Gravity: 2.34
pH: Aqueous solution is neutral.
% Volatiles by volume @ 21C (70F): 0
Boiling Point: Not applicable.
Melting Point: 250 - 270C (482 - 518F)
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): No information found.
Evaporation Rate (BuAc=1): No information found.


10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: May produce acrid smoke and irritating fumes when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizers and strong acids.
Conditions to Avoid: Heat, incompatibles.


11. Toxicological Information

    No LD50/LC50 information found relating to normal routes of occupational exposure.

  --------\Cancer Lists\-----------------------------------------------
                                         ---NTP Carcinogen---
  Ingredient                             Known    Anticipated    IARC Category
  ------------------------------------   -----    -----------    ------
  Sodium Oxalate (62-76-0)                No          No            None

12. Ecological Information

Environmental Fate: No information found.
Environmental Toxicity: No information found.


13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste facility. Although not a listed RCRA hazardous waste, this material may exhibit one or more characteristics of a hazardous waste and require appropriate analysis to determine specific disposal requirements. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.


14. Transport Information

Domestic (Land, D.O.T.)
-----------------------
Proper Shipping Name: TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. (SODIUM OXALATE)
Hazard Class: 6.1, 8
UN/NA: UN2928
Packing Group: II
Information reported for product/size: 2.5KG
International (Water, I.M.O.)
-----------------------------
Proper Shipping Name: TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. (SODIUM OXALATE)
Hazard Class: 6.1, 8
UN/NA: UN2928
Packing Group: II
Information reported for product/size: 2.5KG
International (Air, I.C.A.O.)
-----------------------------
Proper Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. (SODIUM OXALATE)
Hazard Class: 6.1
UN/NA: UN2811
Packing Group: III
Information reported for product/size: 2.5KG


15. Regulatory Information

  --------\Chemical Inventory Status - Part 1\-------------------------
  Ingredient                                       TSCA  EC   Japan  Australia
  -----------------------------------------------  ----  ---  -----  --
  Sodium Oxalate (62-76-0)                          Yes  Yes   Yes      Yes                                      
 
  --------\Chemical Inventory Status - Part 2\-------------------------
                                                          --Canada--
  Ingredient                                       Korea  DSL   NDSL  Phil.
  -----------------------------------------------  -----  ---   ----  -
  Sodium Oxalate (62-76-0)                          Yes   Yes   No     Yes     
 
  --------\Federal, State & International Regulations - Part 1\--------
                                             -SARA 302-    ------SARA 313------
  Ingredient                                 RQ    TPQ     List  Chemical Catg.
  -----------------------------------------  ---   -----   ----  ------
  Sodium Oxalate (62-76-0)                   No    No      No         No
 
  --------\Federal, State & International Regulations - Part 2\--------
                                                        -RCRA-    -TSCA-
  Ingredient                                 CERCLA     261.33     8(d) 
  -----------------------------------------  ------     ------    -----
  Sodium Oxalate (62-76-0)                   No         No         No   
 
Chemical Weapons Convention:  No     TSCA 12(b):  No     CDTA:  No
SARA 311/312:  Acute: Yes      Chronic: Yes  Fire: No  Pressure: No
Reactivity: No          (Pure / Solid) 

Australian Hazchem Code: None allocated.
Poison Schedule: None allocated.
WHMIS: This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.


16. Other Information

Disclaimer: Nile Chemicals. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. NILE CHEMICALS. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, NILE CHEMICALS. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.

 

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