NILE CHEMICALS
Section
1: Chemical Product and Company Identification
Product
Name: Sodium phosphate,
dibasic
CAS#:
7558-79-4
Synonym:
Dibasic Sodium Phosphate;
Disodium hydrogen phosphate; Disodium monohydrogen phosphate;Disodium
orthophosphate; Disodium phosphoric acid;Phosphoric acid, disodium salt; Soda
phosphate; Sodium hydrogen phosphate
Chemical
Name: Sodium Monohydrogen
Phosphate(2:1:1)
Chemical
Formula: Na2HPO4
Section
2: Composition and Information on Ingredients
Composition:
Name
CAS #
% by Weight
Sodium
phosphate, dibasic
7558-79-4
100
Toxicological
Data on Ingredients: Not
applicable.
Section
3: Hazards Identification
Potential
Acute Health Effects: Slightly
hazardous in case of skin contact (irritant), of eye contact (irritant), of
ingestion, of inhalation.
Potential
Chronic Health Effects:CARCINOGENIC
EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS:
Not available.
DEVELOPMENTAL
TOXICITY: Not available. Repeated or prolonged exposure is not known to
aggravate medical condition.
Section
4: First Aid Measures
Eye
Contact:Check for and
remove any contact lenses. In case of contact, immediately flush eyes with
plenty of water for at least 15 minutes. Cold water may be used. Get medical
attention if irritation occurs.
Skin
Contact:Wash with soap and
water. Cover the irritated skin with an emollient. Get medical attention if
irritation develops. Cold water may be used.
Serious
Skin Contact: Not
available.
Inhalation:If
inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical attention.
Serious
Inhalation: Not available.
Ingestion:Do
NOT induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Loosen tight clothing such as a
collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious
Ingestion: Not available.
Section
5: Fire and Explosion Data
Flammability
of the Product: Non-flammable.
Auto-Ignition
Temperature: Not
applicable.
Flash
Points: Not applicable.
Flammable
Limits: Not applicable.
Products
of Combustion: Not
available.
Fire
Hazards in Presence of Various Substances: Not
applicable.
Explosion
Hazards in Presence of Various Substances:
Risks
of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not
available.
Fire
Fighting Media and Instructions: Not
applicable.
Special
Remarks on Fire Hazards: Not
available.
Special
Remarks on Explosion Hazards: Not
available.
Section
6: Accidental Release Measures
Small
Spill:Use appropriate
tools to put the spilled solid in a convenient waste disposal container. Finish
cleaning by spreading water on the contaminated surface and dispose of according
to local and regional authority requirements.
Large
Spill: Use a shovel to put
the material into a convenient waste disposal container.
Section
7: Handling and Storage
Precautions:Do
not ingest. Do not breathe dust. Wear suitable protective clothing. In case of
insufficient ventilation, wear suitable respiratory equipment. If ingested, seek
medical advice immediately and show the container or the label. Keep away from
incompatibles such as acids, alkalis.
Storage:
Keep container tightly
closed. Keep container in a cool, well-ventilated area. Hygroscopic
Section
8: Exposure Controls/Personal Protection
Engineering
Controls:Use process
enclosures, local exhaust ventilation, or other engineering controls to keep
airborne levels below recommended exposure limits. If user operations generate
dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal
Protection: Safety
glasses. Lab coat. Dust respirator. Be sure to use an approved/certified
respirator or equivalent.
Gloves.
Personal
Protection in Case of a Large Spill:Splash
goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing
apparatus should be used to avoid inhalation of the product. Suggested
protective clothing might not be sufficient; consult a specialist BEFORE
handling this product.
Exposure
Limits: Not available.
Section
9: Physical and Chemical Properties
Physical
state and appearance: Solid.
(Solid powder.)
Odor:
Odorless.
Taste:
Saline.
Molecular
Weight: 141.96 g/mole
Color:
White.
pH
(1% soln/water): 9.1
[Basic.]
Boiling
Point: Not available.
Melting
Point:
Decomposition
temperature: 240°C (464°F) Converted to Sodium Pyrophosphate @ about 240 deg.
C
Critical
Temperature: Not
available.
Specific
Gravity: Not available.
Vapor
Pressure: Not applicable.
Vapor
Density: 4.9 (Air = 1)
Volatility:
Not available.
Odor
Threshold: Not available.
Water/Oil
Dist. Coeff.: Not
available.
Ionicity
(in Water): Not available.
Dispersion
Properties: See solubility
in water.
Solubility:
Easily
soluble in hot water. Soluble in cold water. Insoluble in methanol, n-octanol.
Section
10: Stability and Reactivity Data
Stability:
The product is stable.
Instability
Temperature: Not
available.
Conditions
of Instability:
Exposure
to moisture and to incompatible materials. When heated to decompostition, it
emits toxic fumes of phosphoxides and sodium oxide.
Incompatibility
with various substances: Reactive
with acids, alkalis.
Corrosivity:
Not available.
Special
Remarks on Reactivity:
Hygroscopic;
keep container tightly closed. Incompatible with magnesium, alkaloids,
antipyrine, chloral hydrate, lead acetate, pyrogallol, resorcinol, strong
mineral acids, strong organic acids.
Special
Remarks on Corrosivity: Not
available.
Polymerization:
Will not occur.
Section
11: Toxicological Information
Routes
of Entry: Inhalation.
Ingestion.
Toxicity
to Animals: Acute oral
toxicity (LD50): 17000 mg/kg [Rat].
Chronic
Effects on Humans: Not
available.
Other
Toxic Effects on Humans: Slightly
hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Special
Remarks on Toxicity to Animals: Not
available.
Special
Remarks on Chronic Effects on Humans: Not
available.
Special
Remarks on other Toxic Effects on Humans:
Acute
Potential Health Effects: Skin: Causes mild skin irritation. May cause
dermatitis. Eyes: Causes mild eye irritation. Ingestion: May cause irritation of
the digestive tract and may cause purging. It is slowly aborbed. Expected to be
a low ingestion hazard for usual industrial handling. Ingestion of large doses
may affect behavior/central nervous system (tetany). However, if a significant
amount of phosphate is absorbed, hypophosphatemia will occur. Severe
hypophosphatemia may result in hypocalcemia and tetany. Cardiovasular,
respiratory, neurologic, and musculoskeletal effects may occur secondary to
hypernatremia, hypophosphatemia, and hypocalcemia Inhalation: May cause
respiratory tract and mucous membrane irritation. Low hazard for usual
industrial handling. Chronic Potential Health Effects: Skin: High and repeated
exposure may cause dermatitis.
Section
12: Ecological Information
Ecotoxicity:
Not available.
BOD5
and COD: Not available.
Products
of Biodegradation:
Possibly
hazardous short term degradation products are not likely. However, long term
degradation products may arise.
Toxicity
of the Products of Biodegradation: The
product itself and its products of degradation are not toxic.
Special
Remarks on the Products of Biodegradation: Not
available.
Section
13: Disposal Considerations
Waste
Disposal:
Waste
must be disposed of in accordance with federal, state and local environmental
control regulations.
Section
14: Transport Information
DOT
Classification: Not a DOT
controlled material
Identification:
: Not available. UNNA:
9147 PG: III
Special
Provisions for Transport: Not
applicable.
Section
15: Other Regulatory Information
Federal
and State Regulations:
New
York release reporting list: Sodium phosphate, dibasic Pennsylvania RTK: Sodium
phosphate, dibasic Massachusetts RTK: Sodium phosphate, dibasic New Jersey:
Sodium phosphate, dibasic California Director's List of Hazardous Sustances:
Sodium phosphate, dibasic TSCA 8(b) inventory: Sodium phosphate, dibasic CERCLA:
Hazardous substances.: Sodium phosphate, dibasic: 5000 lbs. (2268 kg)
Other
Regulations: EINECS: This
product is on the European Inventory of Existing Commercial Chemical Substances.
Other
Classifications:
WHMIS
(Canada): Not controlled
under WHMIS (Canada).
DSCL
(EEC):
This
product is not classified according to the EU regulations. S24/25- Avoid contact
with skin and eyes.
HMIS
(U.S.A.):
Health
Hazard: 1
Fire
Hazard: 0
Reactivity:
0
Personal
Protection: E
National
Fire Protection Association (U.S.A.):
Health:
1
Flammability:
0
Reactivity:
0
Specific
hazard:
Protective
Equipment:
Gloves.
Lab coat. Dust respirator. Be sure to use an approved/certified respirator or
equivalent. Safety glasses.
Disclaimer: Nile Chemicals. provides the
information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the
appropriate precautionary handling of the material by a properly trained person
using this product. Individuals receiving the information must exercise their
independent judgment in determining its appropriateness for a particular
purpose. NILE CHEMICALS. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS
OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH
HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, NILE
CHEMICALS. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE
UPON THIS INFORMATION.
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