NILE
CHEMICALS
NILE
CHEMICALS
Section
1: Chemical Product and Company Identification
Product
Name: PARA ROSANILINE
CHLORIDE )
CI#:
(C.I.No 42510)
Synonym:
Basic Fuchsin, C.I. 42500,
Basic Red 9 hydrochloride, C.I. Basic Red 9 monohydrochloride;
Paramagenta,
Basic Red 9, C.I. Basic Red 9 hydrochloride, Basic Parafuchsine, Pararosanilin;
4,4'((4-
imino-2,5-cyclohexadien-1-ylidene)methylene)dianiline
monhydrochloride; Pararosaniline Chloride; Pararosaniline Hydrochloride;
p-Fuchsin
Chemical
Name: Benzenamine,
4((4-aminophenyl) (4-imino-2,5-cclohexadien-1-ylidene)methyl),
monohydrochloride
Chemical
Formula: C19-H18-ClN3 or
C19-H17-N3.HCl
Section
2: Composition and Information on Ingredients Composition:
Name
CAS #
% by Weight
Basic
fuchsin 569-61-9
100
Toxicological
Data on Ingredients: Basic
fuchsin: ORAL (LD50): Acute: 5000 mg/kg [Mouse].
Section
3: Hazards Identification Potential Acute Health Effects:
Hazardous
in case of skin contact (permeator), of eye contact (irritant), of ingestion, of
inhalation. Slightly hazardous in case of skin contact (irritant).
Potential
Chronic Health Effects:
Section
4: First Aid Measures Eye Contact:
Skin
Contact: In case of
contact, immediately flush skin with plenty of water. Cover the irritated skin
with an emollient. Remove contaminated clothing and shoes. Wash clothing before
reuse. Thoroughly clean shoes before reuse. Get medical attention.
Serious
Skin Contact: Wash with a
disinfectant soap and cover the contaminated skin with an anti-bacterial cream.
Seek medical attention.
Inhalation:
If inhaled, remove to
fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention.
Serious
Inhalation: Not available.
Ingestion:
Do NOT induce vomiting
unless directed to do so by medical personnel. Never give anything by mouth to
an unconscious person. Loosen tight clothing such as a collar, tie, belt or
waistband. Get medical attention if symptoms appear.
Serious
Ingestion: Not available.
Section
5: Fire and Explosion Data
Flammability
of the Product: May be
combustible at high temperature.
Auto-Ignition
Temperature: Not
available.
Flash
Points: Not available.
Flammable
Limits: Not available.
Products
of Combustion: These
products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...), halogenated
compounds.
Fire
Hazards in Presence of Various Substances:
Slightly
flammable to flammable in presence of heat. Non-flammable in presence of shocks.
Explosion
Hazards in Presence of Various Substances:
Slightly
explosive in presence of open flames and sparks. Non-explosive in presence of
shocks.
Fire
Fighting Media and Instructions:
SMALL
FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not
use water jet.
Special
Remarks on Fire Hazards:
As
with most organic solids, fire is possible at elevated temperatures When heated
to decomposition it emits very toxic fumes of hydrogen chloride and nitrogen
oxides
Special
Remarks on Explosion Hazards:
Fine
dust dispersed in air in sufficient concentrations, and in the presences of an
ignition source is a potential dust explosion hazard.
Section
6: Accidental Release Measures Small Spill:
Use
appropriate tools to put the spilled solid in a convenient waste disposal
container. Finish cleaning by spreading water on the contaminated surface and
dispose of according to local and regional authority requirements.
Large
Spill: Use a shovel to put
the material into a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and allow to evacuate through the
sanitary system.
Section
7: Handling and Storage Precautions:
Keep
away from heat. Keep away from sources of ignition. Do not ingest. Do not
breathe dust. Wear suitable protective clothing. In case of insufficient
ventilation, wear suitable respiratory equipment. If ingested, seek medical
advice immediately and show the container or the label. Avoid contact with skin
and eyes. Keep away from incompatibles such as oxidizing agents, reducing
agents, acids, alkalis.
Storage:
Keep container tightly
closed. Keep container in a cool, well-ventilated area.
Section
8: Exposure Controls/Personal Protection Engineering Controls:
Use
process enclosures, local exhaust ventilation, or other engineering controls to
keep airborne levels below recommended exposure limits. If user operations
generate dust, fume or mist, use ventilation to keep exposure to airborne
contaminants below the exposure limit.
Personal
Protection:
Personal
Protection in Case of a Large Spill:
Exposure
Limits: Not available.
Section
9: Physical and Chemical Properties
Physical
state and appearance: Solid.
(crystalline powder.)
Odor:
Odorless.
Taste:
Not available.
Molecular
Weight: 323.83 g/mole
Color:
Green. (Dark.)
pH
(1% soln/water): Not
available.
Boiling
Point: Not available.
Melting
Point: Decomposition
temperature: 268°C (514.4°F) - 270 C.
Critical
Temperature: Not
available.
Specific
Gravity: Not available.
Vapor
Pressure: Not applicable.
Vapor
Density: Not available.
Volatility:
Not available.
Odor
Threshold: Not available.
Water/Oil
Dist. Coeff.: The product
is more soluble in water; log(oil/water) = -0.2
Ionicity
(in Water): Cationic.
Dispersion
Properties: Not available.
Solubility:
Very slightly soluble in
cold water, diethyl ether. Soluble in alcohol. Solubility in water: 2-3 mg/ml
water. Solubility in ethanol: 2-25 mg/ml ethanol.
Section
10: Stability and Reactivity Data
Stability:
The product is stable.
Instability
Temperature: Not
available.
Conditions
of Instability: Excess
heat, dust generation, incompatible materials
Incompatibility
with various substances: Reactive
with oxidizing agents, reducing agents, acids.
Corrosivity:
Non-corrosive in presence
of glass.
Special
Remarks on Reactivity:
Aniline
is incompatible with acetic anhydride, chlorosulfonic acid, hexachlormelamine,
nitric acid, nitric acid + nitrogen tetroxide and sulfuric acid, nitrobenzene
and glycerin, oleulm, ozone, perchloric acid + formaldehyde, perchromates,
performic acid, trichloromelamine, anilinium chloride,
benzenediazonium-2-carboxylate, boron trichloride, 1-chloro-2,3-epoxypropane,
dibenzoyl peroxide, nitromethane, nitrous acid, and tetranitromethane. Destroyed
by strong oxidizing agents. Readily reduced to leuco-bases with a variety of
reducing agents sensitive to photochemical oxidation.
Special
Remarks on Corrosivity: Not
available.
Polymerization:
Will not occur.
Section
11: Toxicological Information
Routes
of Entry: Absorbed through
skin. Dermal contact. Inhalation. Ingestion.
Toxicity
to Animals: Acute oral
toxicity (LD50): 5000 mg/kg [Mouse].
Chronic
Effects on Humans:
CARCINOGENIC
EFFECTS: Classified 2B (Possible for human.) by IARC. Classified 2 (Some
evidence – anticipated carcinogen.) by NTP. MUTAGENIC EFFECTS: Mutagenic for
mammalian somatic cells. Mutagenic for bacteria and/or yeast. May cause damage
to the following organs: blood, liver, spleen, thyroid.
Other
Toxic Effects on Humans: Hazardous
in case of skin contact (permeator), of ingestion, of inhalation. Slightly
hazardous in case of skin contact (irritant).
Special
Remarks on Toxicity to Animals: Not
available.
Special
Remarks on Chronic Effects on Humans:
May
affect genetic material (mutagenic). May cause cancer.
Section
12: Ecological Information
Ecotoxicity:
Not available.
BOD5
and COD: Not available.
Products
of Biodegradation:
Possibly
hazardous short term degradation products are not likely. However, long term
degradation products may arise.
Toxicity
of the Products of Biodegradation: The
products of degradation are more toxic than the product itself.
Special
Remarks on the Products of Biodegradation: Not
available.
Section
13: Disposal Considerations
Waste
Disposal:
Waste
must be disposed of in accordance with federal, state and local environmental
control regulations.
Section
14: Transport Information
DOT
Classification: Not a DOT
controlled material
Identification:
Not applicable.
Special
Provisions for Transport: Not
applicable.
Section
15: Other Regulatory Information Federal and State Regulations:
Other
Regulations:
OSHA:
Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
EINECS: This product is on the European Inventory of Existing Commercial
Chemical Substances.
Other
Classifications:
WHMIS
(Canada): Not Available
DSCL
(EEC):
R45-
May cause cancer. S36/37- Wear suitable protective clothing and gloves. S45- In
case of accident or if you feel unwell, seek medical advice immediately (show
the label where possible).
HMIS
(U.S.A.):
Health
Hazard: 2
Fire
Hazard: 1
Reactivity:
0
Personal
Protection: E
National
Fire Protection Association (U.S.A.):
Health:
2
Flammability:
1
Reactivity:
0
Specific
hazard:
Protective
Equipment:
Gloves.
Lab coat. Dust respirator. Be sure to use an approved/certified respirator or
equivalent. Splash goggles.
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