NILE
CHEMICALS
NILE
CHEMICALS
Section
1: Chemical Product and Company Identification
Product
Name: Guanidine
hydrochloride
CAS#:
50-01-1
Synonym:
Aminomethanamidine
hydrochloride
Chemical
Formula: CH5N3.HCl
Section
2: Composition and Information on Ingredients
Composition:
Name
CAS # % by Weight
Guanidine
hydrochloride 50-01-1 100
Toxicological
Data on Ingredients: Guanidine
hydrochloride: ORAL (LD50): Acute: 475 mg/kg [Rat].
Section
3: Hazards Identification
Potential
Acute Health Effects:Extremely
hazardous in case of ingestion. Very hazardous in case of skin contact
(irritant), of eye contact (irritant).Inflammation of the eye is characterized
by redness, watering, and itching. Skin inflammation is characterized by
itching, scaling, reddening, or, occasionally, blistering.
Potential
Chronic Health Effects:Extremely
hazardous in case of ingestion. Very hazardous in case of skin contact
(irritant), of eye contact (irritant), of inhalation. CARCINOGENIC EFFECTS: Not
available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to the nervous
system. Repeated or prolonged exposure to the substance can produce target
organs damage. Repeated or prolonged inhalation of dust may lead to chronic
respiratory irritation.
Section
4: First Aid Measures
Eye
Contact:Check for and
remove any contact lenses. Immediately flush eyes with running water for at
least 15 minutes, keeping eyelids open. Cold water may be used. Do not use an
eye ointment. Seek medical attention.
Skin
Contact:After contact with
skin, wash immediately with plenty of water. Gently and thoroughly wash the
contaminated skin with running water and non-abrasive soap. Be particularly
careful to clean folds, crevices, creases and groin. Cold water may be used.
Cover the irritated skin with an emollient. If irritation persists, seek medical
attention. Wash contaminated clothing before reusing.
Serious
Skin Contact:Wash with a
disinfectant soap and cover the contaminated skin with an anti-bacterial cream.
Seek immediate medical attention.
Inhalation:
Allow the victim to rest
in a well ventilated area. Seek immediate medical attention.
Serious
Inhalation: Not available.
Ingestion:Do
not induce vomiting. Examine the lips and mouth to ascertain whether the tissues
are damaged, a possible indication that the toxic material was ingested; the
absence of such signs, however, is not conclusive. Loosen tight clothing such as
a collar, tie, belt or waistband. If the victim is not breathing, perform
mouth-to-mouth resuscitation. Seek immediate medical attention.
Serious
Ingestion: Not available.
Section
5: Fire and Explosion Data
Flammability
of the Product: May be
combustible at high temperature.
Auto-Ignition
Temperature: Not
available.
Flash
Points: Not available.
Flammable
Limits: Not available.
Products
of Combustion: These
products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).
Fire
Hazards in Presence of Various Substances: Not
available.
Explosion
Hazards in Presence of Various Substances:
Risks
of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not
available.
Fire
Fighting Media and Instructions:
SMALL
FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not
use water jet.
Special
Remarks on Fire Hazards: Not
available.
Special
Remarks on Explosion Hazards: Not
available.
Section
6: Accidental Release Measures
Small
Spill:Use appropriate
tools to put the spilled solid in a convenient waste disposal container. Finish
cleaning by spreading water on the contaminated surface and dispose of according
to local and regional authority requirements.
Large
Spill:Use a shovel to put
the material into a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and allow to evacuate through the
sanitary system.
Section
7: Handling and Storage
Precautions:Keep
away from heat. Keep away from sources of ignition. Empty containers pose a fire
risk, evaporate the residue under a fume hood. Ground all equipment containing
material. Do not ingest. Do not breathe dust. If ingested, seek medical advice
immediately and show the container or the label. Avoid contact with skin and
eyes
Storage:Keep
container dry. Keep in a cool place. Ground all equipment containing material.
Keep container tightly closed. Keep in a cool, well-ventilated place.
Combustible materials should be stored away from extreme heat and away from
strong oxidizing agents.
Section
8: Exposure Controls/Personal Protection
Engineering
Controls:Use process
enclosures, local exhaust ventilation, or other engineering controls to keep
airborne levels below recommended exposure limits. If user operations generate
dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal
Protection:Splash goggles.
Lab coat. Dust respirator. Be sure to use an approved/certified respirator or
equivalent. Gloves.
Personal
Protection in Case of a Large Spill:Splash
goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing
apparatus should be used to avoid inhalation of the product. Suggested
protective clothing might not be sufficient; consult a specialist BEFORE
handling this product.
Exposure
Limits: Not available.
Section
9: Physical and Chemical Properties
Physical
state and appearance: Solid.
(Solid crystalline powder.)
Odor:
Not available.
Taste:
Not available.
Molecular
Weight: 95.53 g/mole
Color:
White.
pH
(1% soln/water): 6
[Acidic.]
Boiling
Point: Not available.
Melting
Point: Decomposes.
Critical
Temperature: Not
available.
Specific
Gravity: 1.4 (Water = 1)
Vapor
Pressure: Not applicable.
Vapor
Density: Not available.
Volatility:
Not available.
Odor
Threshold: Not available.
Water/Oil
Dist. Coeff.: Not
available.
Ionicity
(in Water): Not available.
Dispersion
Properties: See solubility
in water, methanol.
Solubility:
Easily soluble in
methanol. Soluble in cold water.
Section
10: Stability and Reactivity Data
Stability:
The product is stable.
Instability
Temperature: Not
available.
Conditions
of Instability: Not
available.
Incompatibility
with various substances: Not
available.
Corrosivity:
Non-corrosive in presence
of glass.
Special
Remarks on Reactivity: Not
available.
Special
Remarks on Corrosivity: Not
available.
Polymerization:
No.
Section
11: Toxicological Information
Routes
of Entry: Eye contact.
Ingestion.
Toxicity
to Animals: Acute oral
toxicity (LD50): 475 mg/kg [Rat].
Chronic
Effects on Humans: The
substance is toxic to the nervous system.
Other
Toxic Effects on Humans:
Extremely
hazardous in case of ingestion. Very hazardous in case of skin contact
(irritant).
Special
Remarks on Toxicity to Animals: Not
available.
Special
Remarks on Chronic Effects on Humans: Not
available.
Special
Remarks on other Toxic Effects on Humans: Not
available.
Section
12: Ecological Information
Ecotoxicity:
Not available.
BOD5
and COD: Not available.
Products
of Biodegradation:
Possibly
hazardous short term degradation products are not likely. However, long term
degradation products may arise.
Toxicity
of the Products of Biodegradation: The
products of degradation are more toxic.
Special
Remarks on the Products of Biodegradation: Not
available.
Section
13: Disposal Considerations
Waste
Disposal:
Section
14: Transport Information
DOT
Classification: Not a DOT
controlled material (United States).
Identification:
Not applicable.
Special
Provisions for Transport: Not
applicable.
Section
15: Other Regulatory Information
Federal
and State Regulations: TSCA
8(b) inventory: Guanidine hydrochloride
Other
Regulations: OSHA:
Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other
Classifications:
WHMIS
(Canada):
CLASS
D-1B: Material causing immediate and serious toxic effects (TOXIC). CLASS D-2B:
Material causing other toxic effects (TOXIC).
DSCL
(EEC):
R22-
Harmful if swallowed. R38- Irritating to skin. R41- Risk of serious damage to
eyes.
HMIS
(U.S.A.):
Health
Hazard: 2
Fire
Hazard: 1
Reactivity:
0
Personal
Protection: E
National
Fire Protection Association (U.S.A.):
Health:
2
Flammability:
1
Reactivity:
0
Specific
hazard:
Protective
Equipment:
Gloves.
Lab coat. Dust respirator. Be sure to use an approved/certified respirator or
equivalent.Wear appropriate respirator when ventilation is inadequate. Splash
goggles.
Disclaimer: Nile Chemicals. provides the
information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the
appropriate precautionary handling of the material by a properly trained person
using this product. Individuals receiving the information must exercise their
independent judgment in determining its appropriateness for a particular
purpose. NILE CHEMICALS. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS
OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH
HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, NILE
CHEMICALS. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE
UPON THIS INFORMATION.
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