NILE CHEMICALS
Section
1: Chemical Product and Company Identification
Product
Name: Chloranillic acid Barium Salt
CAS#:
13435-46-6(anhydrous);
32458-20-1(trihydrate)
Synonym:
Chloranilic acid barium salt trihydrate
Chemical
Name: 2,5-Cyclohexadiene-1,4-dione, 2,5-
dichloro-3,6-dihydroxy-,
barium salt (1:1), trihydrate, Barium Chloranilate, Trihydrate
Chemical
Formula: C6-Ba-Cl2-O.3H2O
Section
2: Composition and Information on Ingredients
Composition:
Name
CAS # % by
Weight
Barium
Chloranilate, Trihydrate 13435-46-6 10 (anhydrous);
32458-20-1(trihydrate)
Toxicological
Data on Ingredients: Barium Chloranilate,
Trihydrate LD50: Not available. LC50: Not available.
Section
3: Hazards Identification
Potential
Acute Health Effects:
Hazardous
in case of ingestion, of inhalation. Slightly hazardous in case of skin contact
(irritant), of eye contact (irritant).
Potential
Chronic Health Effects:
CARCINOGENIC
EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS:
Not available.
DEVELOPMENTAL
TOXICITY: Not available. The substance may be toxic to kidneys, the nervous
system, liver, heart, spleen, gastrointestinal tract, bone marrow. Repeated or
prolonged exposure to the substance can produce target organs damage.
Section
4: First Aid Measures
Eye
Contact:
Check
for and remove any contact lenses. In case of contact, immediately flush eyes
with plenty of water for at least 15 minutes. Cold water may be used. Get
medical attention if irritation occurs.
Skin
Contact:
Wash
with soap and water. Cover the irritated skin with an emollient. Get medical
attention if irritation develops. Cold water may be used.
Serious
Skin Contact: Not available.
Inhalation:
If
inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical attention.
Serious
Inhalation: Not available.
Ingestion:
Do
NOT induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. If large quantities of this material
are swallowed, call a physician immediately. Loosen tight clothing such as a
collar, tie, belt or waistband.
Serious
Ingestion: Not available.
Section
5: Fire and Explosion Data
Flammability
of the Product: Non-flammable.
Auto-Ignition
Temperature: Not applicable.
Flash
Points: Not applicable.
Flammable
Limits: Not applicable.
Products
of Combustion: Not available.
Fire
Hazards in Presence of Various Substances: Not
applicable.
Explosion
Hazards in Presence of Various Substances:
Risks
of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not
available.
Fire
Fighting Media and Instructions: Not
applicable.
Special
Remarks on Fire Hazards: Not available.
Special
Remarks on Explosion Hazards: Not
available.
Section
6: Accidental Release Measures
Small
Spill:
Use
appropriate tools to put the spilled solid in a convenient waste disposal
container. Finish cleaning by spreading water on the contaminated surface and
dispose of according to local and regional authority requirements.
Large
Spill:
Use
a shovel to put the material into a convenient waste disposal container. Finish
cleaning by spreading water on the contaminated surface and allow to evacuate
through the sanitary system.
Section
7: Handling and Storage
Precautions:
Do
not ingest. Do not breathe dust. Wear suitable protective clothing. In case of
insufficient ventilation, wear suitable respiratory equipment. If ingested, seek
medical advice immediately and show the container or the label. Keep away from
incompatibles such as oxidizing agents.
Storage:
Keep container tightly closed. Keep
container in a cool, well-ventilated area.
Section
8: Exposure Controls/Personal Protection
Engineering
Controls:
Use
process enclosures, local exhaust ventilation, or other engineering controls to
keep airborne levels below recommended exposure limits. If user operations
generate dust, fume or mist, use ventilation to keep exposure to airborne
contaminants below the exposure limit.
Personal
Protection: Safety glasses. Lab coat. Dust
respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal
Protection in Case of a Large Spill:
Splash
goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing
apparatus should be used to avoid inhalation of the product. Suggested
protective clothing might not be sufficient; consult a specialist BEFORE
handling this product.
Exposure
Limits: Not available.
Section
9: Physical and Chemical Properties
Physical
state and appearance: Solid. (Powdered
solid.)
Odor:
Odorless.
Taste:
Not available.
Molecular
Weight: 398.35 g/mole
Color:
Yellow or brown.
pH
(1% soln/water): Not available.
Boiling
Point: Not available.
Melting
Point: >300°C (572°F)
Critical
Temperature: Not available.
Specific
Gravity: Not available.
Vapor
Pressure: Not applicable.
Vapor
Density: Not available.
Volatility:
Not available.
Odor
Threshold: Not available.
Water/Oil
Dist. Coeff.: Not available.
Ionicity
(in Water): Not available.
Dispersion
Properties: See solubility in water.
Solubility:
Soluble in cold water, hot water.
Section
10: Stability and Reactivity Data
Stability:
The product is stable.
Instability
Temperature: Not available.
Conditions
of Instability: Dust generation,
incompatible materials
Incompatibility
with various substances: Reactive with
oxidizing agents.
Corrosivity:
Not available.
Special
Remarks on Reactivity: Not available.
Special
Remarks on Corrosivity: Not available.
Polymerization:
Will not occur.
Section
11: Toxicological Information
Routes
of Entry: Inhalation. Ingestion.
Toxicity
to Animals:
LD50:
Not available. LC50: Not available.
Chronic
Effects on Humans:
May
cause damage to the following organs: kidneys, the nervous system, liver, heart,
spleen, gastrointestinal tract, bone marrow.
Other
Toxic Effects on Humans:
Hazardous
in case of ingestion, of inhalation. Slightly hazardous in case of skin contact
(irritant).
Special
Remarks on Toxicity to Animals: Not
available.
Special
Remarks on Chronic Effects on Humans: Not
available.
Special
Remarks on other Toxic Effects on Humans:
Potential
Health Effects: Skin: May cause skin irritation. Eyes: May cause eye irritation.
Inhalation: May be harmful if inhaled. May cause respiratory tract and mucous
membrane irritation. Ingestion: May be harmful if swallowed. Ingestion of Barium
and soluble Barium compounds can cause gastroenteritis, stomach pains, nausea,
vomiting, diarrhea, increased salivation muscular paralysis, contractions of the
smooth, striated and cardiac muscles, slow irregular, pulse, dysrhythmia,
hypertension, bradycardia, cardiac shock, shallow breathing, tachypnea,
respiratory failure, mydriasis, profound hypokalemia, metabolic acidosis,
dizziness, seizures, temors, liver damage, renal failure.
Section
12: Ecological Information
Ecotoxicity:
Not available.
BOD5
and COD: Not available.
Products
of Biodegradation:
Possibly
hazardous short term degradation products are not likely. However, long term
degradation products may arise.
Toxicity
of the Products of Biodegradation: The
products of degradation are as toxic as the product itself.
Special
Remarks on the Products of Biodegradation: Not
available.
Section
13: Disposal Considerations
Waste
Disposal:
Waste
must be disposed of in accordance with federal, state and local environmental
control regulations.
Section
14: Transport Information
DOT
Classification: Not a DOT controlled
material
Identification:
Not applicable.
Special
Provisions for Transport: Not applicable.
Section
15: Other Regulatory Information
Federal
and State Regulations:
TSCA
8(b)Inventory: Barium Chloranilate (CAS no. 13435-46-6) Barium Chloranilate
trihydrate (CAS no. 32458-20-1) is not TSCA listed
Other
Regulations:
OSHA:
Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
EINECS: This product is on the European Inventory of Existing Commercial
Chemical Substances.
Other
Classifications:
WHMIS
(Canada): Not controlled under WHMIS
(Canada).
DSCL
(EEC):
R20/22-
Harmful by inhalation and if swallowed. S28- After contact with skin, wash
immediately with plenty of water. S36/37/39- Wear suitable protective clothing,
gloves and eye/face protection. S45- In case of accident or if you feel unwell,
seek medical advice immediately (show the label where possible).
HMIS
(U.S.A.):
Health
Hazard: 2
Fire
Hazard: 0
Reactivity:
0
Personal
Protection: E
National
Fire Protection Association (U.S.A.):
Health:
2
Flammability:
0
Reactivity:
0
Specific
hazard:
Protective
Equipment:
Gloves.
Lab coat. Dust respirator. Be sure to use an approved/certified respirator or
equivalent. Safety glasses.
Disclaimer: Nile Chemicals. provides the
information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the
appropriate precautionary handling of the material by a properly trained person
using this product. Individuals receiving the information must exercise their
independent judgment in determining its appropriateness for a particular
purpose. NILE CHEMICALS. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS
OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH
HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, NILE
CHEMICALS. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE
UPON THIS INFORMATION.
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