NILE
CHEMICALS
NILE
CHEMICALS
Section
1: Chemical Product and Company Identification
Product
Name: 4-Bromobenzaldehyde
CAS#:
1122-91-4
Synonym:
para-Bromobenzaldehyde
Chemical
Name: Not available.
Chemical
Formula: C7H5BrO
Section
2: Composition and Information on IngredientsComposition:
Name
CAS # % by Weight
{4-}Bromobenzaldehyde
1122-91-4 100
Toxicological
Data on Ingredients: 4-Bromobenzaldehyde:
ORAL (LD50): Acute: 1230 mg/kg [Mouse].
Section
3: Hazards Identification
Potential
Acute Health Effects:
Very
hazardous in case of skin contact (irritant), of eye contact (irritant).
Hazardous in case of ingestion, of inhalation. Slightly hazardous in case of
skin contact (permeator). Inflammation of the eye is characterized by redness,
watering, and itching. Skin inflammation is characterized by itching, scaling,
reddening, or, occasionally, blistering.
Potential
Chronic Health Effects: CARCINOGENIC
EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS:
Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged
exposure is not known to aggravate medical condition.
Section
4: First Aid Measures Eye Contact:
Check
for and remove any contact lenses. In case of contact, immediately flush eyes
with plenty of water for at least 15 minutes. Get medical attention immediately.
Skin
Contact: In case of
contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Cover the irritated skin with an
emollient. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get
medical attention immediately.
Serious
Skin Contact: Wash with a
disinfectant soap and cover the contaminated skin with an anti-bacterial cream.
Seek immediate medical attention.
Inhalation:
If inhaled, remove to
fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention.
Serious
Inhalation: Not available.
Ingestion:
Do
NOT induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. If large quantities of this material
are swallowed, call a physician immediately. Loosen tight clothing such as a
collar, tie, belt or waistband.
Serious
Ingestion: Not available.
Section
5: Fire and Explosion Data
Flammability
of the Product: May be
combustible at high temperature.
Auto-Ignition
Temperature: Not
available.
Flash
Points: CLOSED CUP: 108°C
(226.4°F).
Flammable
Limits: Not available.
Products
of Combustion: These
products are carbon oxides (CO, CO2), halogenated compounds.
Fire
Hazards in Presence of Various Substances: Not
available.
Explosion
Hazards in Presence of Various Substances:
Risks
of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not
available.
Fire
Fighting Media and Instructions: SMALL
FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not
use water jet.
Special
Remarks on Fire Hazards: Not
available.
Special
Remarks on Explosion Hazards: Not
available.
Section
6: Accidental Release Measures Small Spill:
Use
appropriate tools to put the spilled solid in a convenient waste disposal
container. Finish cleaning by spreading water on the contaminated surface and
dispose of according to local and regional authority requirements.
Large
Spill: Use a shovel to put
the material into a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and allow to evacuate through the
sanitary system.
Section
7: Handling and Storage Precautions:
Keep
away from heat. Keep away from sources of ignition. Empty containers pose a fire
risk, evaporate the residue under a fume hood. Ground all equipment containing
material. Do not ingest. Do not breathe dust. In case of insufficient
ventilation, wear suitable respiratory equipment. If ingested, seek medical
advice immediately and show the container or the label. Avoid
contact
with skin and eyes.
Storage:
Keep container tightly
closed. Keep container in a cool, well-ventilated area.
Section
8: Exposure Controls/Personal Protection Engineering Controls:
Use
process enclosures, local exhaust ventilation, or other engineering controls to
keep airborne levels below recommended exposure limits. If user operations
generate dust, fume or mist, use ventilation to keep exposure to airborne
contaminants below the exposure limit.
Personal
Protection: Splash
goggles. Lab coat. Dust respirator. Be sure to use an approved/certified
respirator or equivalent. Gloves.
Personal
Protection in Case of a Large Spill: Splash
goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing
apparatus should be used to avoid inhalation of the product. Suggested
protective clothing might not be sufficient; consult a specialist BEFORE
handling this
product.
Exposure
Limits: Not available.
Section
9: Physical and Chemical Properties
Physical
state and appearance: Solid.
Odor:
Not available.
Taste:
Not available.
Molecular
Weight: 185.02 g/mole
Color:
Not available.
pH
(1% soln/water): Not
available.
Boiling
Point: Not available.
Melting
Point: 56°C (132.8°F)
Critical
Temperature: Not
available.
Specific
Gravity: Not available.
Vapor
Pressure: Not applicable.
Vapor
Density: Not available.
Volatility:
Not available.
Odor
Threshold: Not available.
Water/Oil
Dist. Coeff.: Not
available.
Ionicity
(in Water): Not available.
Dispersion
Properties: Not available.
Solubility:
Not available.
Section
10: Stability and Reactivity Data
Stability:
The product is stable.
Instability
Temperature: Not
available.
Conditions
of Instability: Not
available.
Incompatibility
with various substances: Not
available.
Corrosivity:
Non-corrosive in presence
of glass.
Special
Remarks on Reactivity: Not
available.
Special
Remarks on Corrosivity: Not
available.
Polymerization:
Will not occur.
Section
11: Toxicological Information
Routes
of Entry: Eye contact.
Inhalation. Ingestion.
Toxicity
to Animals: Acute oral
toxicity (LD50): 1230 mg/kg [Mouse].
Chronic
Effects on Humans: Not
available.
Other
Toxic Effects on Humans: Very
hazardous in case of skin contact (irritant). Hazardous in case of ingestion, of
inhalation. Slightly hazardous in case of skin contact (permeator).
Special
Remarks on Toxicity to Animals: Not
available.
Special
Remarks on Chronic Effects on Humans: Not
available.
Special
Remarks on other Toxic Effects on Humans: Not
available.
Section
12: Ecological Information
Ecotoxicity:
Not available.
BOD5
and COD: Not available.
Products
of Biodegradation: Possibly
hazardous short term degradation products are not likely. However, long term
degradation products may arise.
Toxicity
of the Products of Biodegradation: The
products of degradation are more toxic.
Special
Remarks on the Products of Biodegradation: Not
available.
Section
13: Disposal Considerations
Waste
Disposal:
Section
14: Transport Information
DOT
Classification: Not a DOT
controlled material (United States).
Identification:
Not applicable.
Special
Provisions for Transport: No
DOT, ref 49CFR, 173.150
Section
15: Other Regulatory Information
Federal
and State Regulations: TSCA
8(b) inventory: 4-Bromobenzaldehyde
Other
Regulations: OSHA:
Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other
Classifications:
WHMIS
(Canada): CLASS D-2B:
Material causing other toxic effects (TOXIC).
DSCL
(EEC):
R38-
Irritating to skin. R41- Risk of serious damage to eyes.
HMIS
(U.S.A.):
Health
Hazard: 2
Fire
Hazard: 1
Reactivity:
0
Personal
Protection: E
National
Fire Protection Association (U.S.A.):
Health:
2
Flammability:
1
Reactivity:
0
Specific
hazard:
Protective
Equipment: Gloves. Lab
coat. Dust respirator. Be sure to use an approved/certified respirator or
equivalent. Wear appropriate respirator when ventilation is inadequate. Splash
goggles.
Disclaimer: Nile Chemicals. provides the
information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the
appropriate precautionary handling of the material by a properly trained person
using this product. Individuals receiving the information must exercise their
independent judgment in determining its appropriateness for a particular
purpose. NILE CHEMICALS. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS
OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH
HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, NILE
CHEMICALS. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE
UPON THIS INFORMATION.
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