NILE
CHEMICALS
SAFETY DATA SHEET
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
1.1 Product identifiers
Product name : 4 -
Aminoacetophenone
Product Number : A38002
CAS-No. : 99-92-3
1.2 Relevant identified uses of the substance or mixture and uses advised
against
Identified uses : Laboratory chemicals, Manufacture of substances
1.4 Emergency telephone number
Emergency Phone # : +91-9880711432
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 4), H302
Skin irritation (Category 2), H315
Eye irritation (Category 2), H319
Specific target organ toxicity - single exposure (Category 3), H335
For the full text of the H-Statements mentioned in this Section, see
Section 16.
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Xn Harmful R22, R36/37/38
For the full text of the R-phrases mentioned in this Section, see Section
16.
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Hazard statement(s)
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
2.3 Other hazards - none
SECTION 3: Composition/information on ingredients
3.1 Substances
Synonyms : 4-Acetylaniline
Formula : C8H9NO
Molecular Weight : 135,16 g/mol
CAS-No. : 99-92-3
EC-No. : 202-801-2
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
4'-Aminoacetophenone
Acute Tox. 4; Skin Irrit. 2; Eye Irrit.
2; STOT SE 3; H302, H315, H319,
H335
-
Hazardous ingredients according to Directive 1999/45/EC
Component Classification Concentration
4'-Aminoacetophenone
Xn, R22 - R36/37/38 -
For the full text of the H-Statements and R-Phrases mentioned in this
Section, see Section 16
SECTION 4: First aid measures
4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in
attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give
artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a
physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with
water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the
labelling (see section 2.2) and/or in
section 11
4.3 Indication of any immediate medical attention and special treatment
needed
no data available
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides, nitrogen oxides (NOx)
5.3 Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
5.4 Further information
no data available
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing
vapours, mist or gas. Ensure
adequate ventilation. Evacuate personnel to safe areas. Avoid breathing
dust.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product
enter drains. Discharge into the
environment must be avoided.
6.3 Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel.
Keep in suitable, closed
containers for disposal.
6.4 Reference to other sections
For disposal see section 13.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is
formed.Normal measures for preventive fire
protection.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and
well-ventilated place.
7.3 Specific end use(s)
A part from the uses mentioned in section 1.2 no other specific uses are
stipulated
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash
hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye
protection tested
and approved under appropriate government standards such as NIOSH (US) or
EN 166(EU).
contaminated gloves after use in accordance with applicable laws and good
laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU
Directive 89/686/EEC and
the standard EN 374 derived from it.
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Body Protection
Complete suit protecting against chemicals, The type of protective
equipment must be selected
according to the concentration and amount of the dangerous substance at the
specific workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle
respirator.For higher
level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143)
respirator cartridges.
Use respirators and components tested and approved under appropriate
government standards
such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product
enter drains. Discharge into
the environment must be avoided.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
a) Appearance Form: powder
Colour: light yellow, dark yellow
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing
point
Melting point/range: 103 - 107 °C - lit.
f) Initial boiling point and
boiling range
293 °C - lit.
g) Flash point no data available
h) Evapouration rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower
flammability or
explosive limits
no data available
k) Vapour pressure no data available
l) Vapour density no data available
m) Relative density no data available
n) Water solubility no data available
o) Partition coefficient: noctanol/
water
no data available
p) Auto-ignition
temperature
no data available
q) Decomposition
temperature
no data available
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
9.2 Other safety information
no data available
SECTION 10: Stability and reactivity
10.1 Reactivity
no data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
no data available
10.4 Conditions to avoid
no data available
10.5 Incompatible materials
acids, Acid chlorides, Acid anhydrides, Chloroformates, Strong oxidizing
agents, Strong reducing agents
10.6 Hazardous decomposition products
Other decomposition products - no data available
In the event of fire: see section 5
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - rat - 381 mg/kg
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal
to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single
exposure
Inhalation - May cause respiratory irritation.
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS: AM5500000
Absorption into the body leads to the formation of methemoglobin which in
sufficient concentration causes
cyanosis. Onset may be delayed 2 to 4 hours or longer., To the best of our
knowledge, the chemical,
physical, and toxicological properties have not been thoroughly
investigated.
SECTION 12: Ecological information
12.1 Toxicity
Toxicity to daphnia and
other aquatic
invertebrates
EC50 - Daphnia magna (Water flea) - 5 mg/l - 48 h
12.2 Persistence and degradability
no data available
12.3 Bioaccumulative potential
no data available
12.4 Mobility in soil
no data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not
required/not conducted
12.6 Other adverse effects
Toxic to aquatic life.
no data available
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contact a licensed
professional waste disposal service to dispose of this material. Dissolve
or mix the material with a
combustible solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.
SECTION 14: Transport information
14.1 UN number
ADR/RID: - IMDG: - IATA: -
14.2 UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
14.3 Transport hazard class(es)
ADR/RID: - IMDG: - IATA: -
14.4 Packaging group
ADR/RID: - IMDG: - IATA: -
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
no data available
SECTION 15: Regulatory information
This safety datasheet complies with the requirements of Regulation (EC) No.
1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for
the substance or mixture
no data available
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
SECTION 16: Other information
The above information is believed to be correct but does not purport to be
all inclusive and shall be
used only as a guide. The information in this document is based on the
present state of our knowledge
and is applicable to the product with regard to appropriate safety
precautions. It does not represent any
guarantee of the properties of the product. Nile Chemicals and its
Affiliates shall not be held liable
for
any damage resulting from handling or from
contact with the above product.
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