NILE CHEMICALS
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
1.1 Product identifiers
Product name : 2-Bromoaniline
CAS-No. : 615-36-1
Relevant identified uses of the substance or mixture and uses
advised against
Identified uses : Laboratory chemicals, Manufacture of substances
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
[EU-GHS/CLP]
Acute toxicity, Oral (Category 4)
Acute toxicity, Dermal (Category 3)
Specific target organ toxicity - repeated exposure (Category 2)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Toxic in contact with skin and if swallowed. Danger of cumulative
effects. Harmful to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal word Danger
Hazard statement(s)
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H373 May cause damage to organs through prolonged or repeated
exposure.
Precautionary statement(s)
P280 Wear protective gloves/ protective clothing.
P312 Call a POISON CENTER or doctor/ physician if you feel unwell.
Supplemental Hazard Statements none
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
R-phrase(s)
R24/25 Toxic in contact with skin and if swallowed.
R33 Danger of cumulative effects.
R52/53 Harmful to aquatic organisms, may cause long-term adverse
effects in
the aquatic environment.
S-phrase(s)
S36/37 Wear suitable protective clothing and gloves.
S45 In case of accident or if you feel unwell, seek medical advice
immediately
(show the label where possible).
S61 Avoid release to the environment. Refer to special
instructions/ Safety
data sheets.
Other hazards - none
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Formula : C6H6BrN
Molecular Weight : 172,02 g/mol
Component Concentration
2-Bromoaniline
CAS-No.
EC-No.
615-36-1
210-421-3
4. FIRST AID MEASURES
Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in
attendance.
If inhaled If breathed in, move person into fresh air. If not breathing, give
artificial respiration. Consult a physician.
In case of skin contact Wash off with soap and plenty of water. Take victim immediately to
hospital. Consult a physician.
In case of eye contact Flush eyes with water as a precaution.
If swallowed Never give anything by mouth to an unconscious person. Rinse mouth
with water. Consult a physician.
Most important symptoms and effects, both acute and delayed Absorption into the body leads to the formation of methemoglobin
which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4
hours or longer., To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
Indication of any immediate medical attention and special treatment
needed no data available
5. FIRE-FIGHTING MEASURES
Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon
dioxide.
Special hazards arising from the substance or mixture Carbon oxides, nitrogen oxides (NOx), Hydrogen bromide gas
dvice for firefighters Wear self contained breathing apparatus for fire fighting if
necessary.
Further information no data available
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid dust formation. Avoid
breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel
to safe areas. Avoid breathing dust.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let
product enter drains. Discharge into the environment must be avoided.
Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep
up and shovel. Keep in suitable, closed containers for disposal.
Reference to other sections For disposal see section 13.
7. HANDLING AND STORAGE
Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and
aerosols.
Provide appropriate exhaust ventilation at places where dust is
formed.Normal measures for preventive fire protection.
Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and
well-ventilated place.
Specific end uses no data available
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls Avoid contact with skin, eyes and clothing. Wash hands before
breaks and immediately after handling the product.
Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection
tested and approved under appropriate government standards such as NIOSH (US) or
EN 166(EU).
Skin protection Handle with gloves. Gloves must be inspected prior to use. Use
proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with
this product. Dispose of
contaminated gloves after use in accordance with applicable laws
and good laboratory practices.
Wash and dry hands. The selected protective gloves have to satisfy
the specifications of EU Directive 89/686/EEC and the standard EN 374 derived
from it.
Body Protection Complete suit protecting against chemicals, The type of protective
equipment must be selected
according to the concentration and amount of the dangerous
substance at the specific workplace.
Respiratory protection Where risk assessment shows air-purifying respirators are
appropriate use a full-face particle
respirator type N99 (US) or type P2 (EN 143) respirator cartridges
as a backup to engineering
controls. If the respirator is the sole means of protection, use a
full-face supplied air respirator. Use
respirators and components tested and approved under appropriate
government standards such as
NIOSH (US) or CEN (EU).
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
a) Appearance Form: Solidified mass or fragments Colour: light
brown
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing point Melting point/range: 24 - 28 °C -
lit.
f) Initial boiling point and boiling range 229 °C - lit.
g) Flash point no data available
h) Evaporation rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower flammability or explosive limits no data available
k) Vapour pressure no data available
l) Vapour density no data available
m) Relative density 1,52 g/cm3 at 25 °C
n) Water solubility no data available
o) Partition coefficient: noctanol/ water log Pow: 2,11
p) Autoignition temperature no data available
q) Decomposition temperature no data available
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
Other safety information
no data available
10. STABILITY AND REACTIVITY
Reactivity no data available
Chemical stability no data available
Possibility of
hazardous reactions no data available
Conditions to avoid no data available
Incompatible materials acids, Acid chlorides, Acid anhydrides, Chloroformates, Strong
oxidizing agents
Hazardous decomposition
products Other decomposition products - no data available
11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity no data available
Skin corrosion/irritation no data available
Serious eye damage/eye irritation no data available
Respiratory or skin sensitization no data available
Germ cell mutagenicity no data available
Carcinogenicity IARC: No component of this product present at levels greater than
or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity no data available
Specific target organ toxicity - single exposure no data available
Specific target organ toxicity - repeated exposure May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard no data available
Potential health effects Inhalation Harmful if inhaled. May cause
respiratory tract irritation.
Ingestion Harmful if swallowed.
Skin Toxic if absorbed through skin. May
cause skin irritation.
Eyes May cause eye irritation.
Signs and Symptoms of Exposure Absorption into the body leads to the formation of methemoglobin
which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4
hours or longer., To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
Additional Information RTECS: Not available
12. ECOLOGICAL INFORMATION
Toxicity Toxicity to daphnia and other aquatic invertebrates.
EC50 - Daphnia magna (Water flea) - 3 mg/l - 48 h
Persistence and degradability no data available
Bioaccumulative potential no data available
Mobility in soil no data available
Results of PBT and vPvB assessment no data available
Other adverse effects Toxic to aquatic life. no data available
13. DISPOSAL CONSIDERATIONS
Waste treatment methods Product
Offer surplus and non-recyclable solutions to a licensed disposal
company. Contact a licensed professional waste disposal service to dispose of
this material. Dissolve or mix the material with a combustible solvent and burn
in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.
14. TRANSPORT INFORMATION
UN number
ADR/RID: 2811 IMDG: 2811 IATA: 2811
UN proper shipping name
ADR/RID: TOXIC SOLID, ORGANIC, N.O.S. (2-Bromoaniline)
IMDG: TOXIC SOLID, ORGANIC, N.O.S. (2-Bromoaniline)
IATA: Toxic solid, organic, n.o.s. (2-Bromoaniline)
Transport hazard class(es)
ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1
Packaging group
ADR/RID: III IMDG: III IATA: III
Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
Special precautions for user
no data available
15. REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation
(EC) No. 1907/2006.
Safety, health and environmental regulations/legislation specific
for the substance or mixture
no data available
Chemical Safety Assessment
no data available
Disclaimer: Nile Chemicals. provides the
information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the
appropriate precautionary handling of the material by a properly trained person
using this product. Individuals receiving the information must exercise their
independent judgment in determining its appropriateness for a particular
purpose. NILE CHEMICALS. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS
OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH
HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, NILE
CHEMICALS. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE
UPON THIS INFORMATION.
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