NILE CHEMICALS
1.
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product
identifiers
Product
name : 1,10-Phenanthroline monohydrochloride monohydrate
CAS-No.
: 18851-33-7
2.
HAZARDS IDENTIFICATION
Classification
of the substance or mixture
Classification
according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Acute
toxicity, Oral (Category 3)
Acute
aquatic toxicity (Category 1)
Chronic
aquatic toxicity (Category 1)
Classification
according to EU Directives 67/548/EEC or 1999/45/EC
Toxic
if swallowed. Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic
environment.
According
to European Directive 67/548/EEC as amended.
Hazard
symbol(s)
R-phrase(s)
R25
Toxic if swallowed.
R50/53
Very toxic to aquatic organisms, may cause long-term adverse effects in
the
aquatic environment.
S-phrase(s)
S45
In case of accident or if you feel unwell, seek medical advice immediately
(show
the label where possible).
S60
This material and its container must be disposed of as hazardous waste.
S61
Avoid release to the environment. Refer to special instructions/ Safety
data
sheets.
Caution
- substance not yet tested completely.
Other
hazards - none
3.
COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Synonyms
: 1,10-Phenanthroline chloride monohydrate
Formula
: C12H8N2 · HCl · H2O
Molecular
Weight : 234,68 g/mol
Component
Concentration
1,10-Phenanthroline
chloride monohydrate
CAS-No.
EC-No.
18851-33-7
223-325-1
4.
FIRST AID MEASURES
Description
of first aid measures
General
advice Consult a physician. Show this
safety data sheet to the doctor in attendance.
If
inhaled If breathed in, move person into
fresh air. If not breathing, give artificial respiration. Consult a physician.
In
case of skin contact Wash off with soap and
plenty of water. Take victim immediately to hospital. Consult a physician.
In
case of eye contact Flush eyes with water
as a precaution.
If
swallowed Never give anything by mouth to
an unconscious person. Rinse mouth with water. Consult a physician.
Most
important symptoms and effects, both acute and delayed To
the best of our knowledge, the chemical, physical, and toxicological properties
have not been thoroughly investigated.
Indication
of any immediate medical attention and special treatment needed no
data available
5.
FIRE-FIGHTING MEASURES
Extinguishing
media
Suitable
extinguishing media Use water spray,
alcohol-resistant foam, dry chemical or carbon dioxide.
Special
hazards arising from the substance or mixture Carbon
oxides, nitrogen oxides (NOx), Hydrogen chloride gas
Advice
for firefighters Wear self contained
breathing apparatus for fire fighting if necessary.
Further
information no data available
6.
ACCIDENTAL RELEASE MEASURES
Personal
precautions, protective equipment and emergency procedures
Wear
respiratory protection. Avoid dust formation. Avoid breathing vapors, mist or
gas. Ensure adequate
ventilation.
Evacuate personnel to safe areas. Avoid breathing dust.
Environmental
precautions Prevent further leakage or
spillage if safe to do so. Do not let product enter drains. Discharge into the
environment
must be avoided.
Methods
and materials for containment and cleaning up
Pick
up and arrange disposal without creating dust. Sweep up and shovel. Keep in
suitable, closed
containers
for disposal.
Reference
to other sections For disposal see section
13.
7.
HANDLING AND STORAGE
Precautions
for safe handling Avoid contact with skin
and eyes. Avoid formation of dust and aerosols.
Provide
appropriate exhaust ventilation at places where dust is formed.Normal measures
for preventive fire
protection.
Conditions
for safe storage, including any incompatibilities Store
in cool place. Keep container tightly closed in a dry and well-ventilated place.
hygroscopic
Specific
end uses no data available
8.
EXPOSURE CONTROLS/PERSONAL PROTECTION
Control
parameters
Components
with workplace control parameters
Exposure
controls
Appropriate
engineering controls Avoid contact with
skin, eyes and clothing. Wash hands before breaks and immediately after handling
the
product.
Personal
protective equipment Eye/face protection
Face
shield and safety glasses Use equipment for eye protection tested and approved
under
appropriate
government standards such as NIOSH (US) or EN 166(EU).
Skin
protection Handle with gloves. Gloves must
be inspected prior to use. Use proper glove removal technique
(without
touching glove's outer surface) to avoid skin contact with this product. Dispose
of
contaminated
gloves after use in accordance with applicable laws and good laboratory
practices.
Wash
and dry hands.
Body
Protection Complete suit protecting against
chemicals, The type of protective equipment must be selected
according
to the concentration and amount of the dangerous substance at the specific
workplace.
Respiratory
protection Where risk assessment shows
air-purifying respirators are appropriate use a full-face particle
respirator
type N99 (US) or type P2 (EN 143) respirator cartridges as a backup to
engineering
controls.
9.
PHYSICAL AND CHEMICAL PROPERTIES
Information
on basic physical and chemical properties
a)
Appearance Form: solid
b)
Odour no data available
c)
Odour Threshold no data available
d)
pH no data available
e)
Melting point/freezing point no data available
f)
Initial boiling point and boiling range no data available
g)
Flash point no data available
h)
Evaporation rate no data available
i)
Flammability (solid, gas) no data available
j)
Upper/lower flammability or explosive limits no data available
k)
Vapour pressure no data available
l)
Vapour density no data available
m)
Relative density no data available
n)
Water solubility 0,1 g/l - soluble
o)
Partition coefficient: noctanol/water no data available
p)
Autoignition temperature no data available
q)
Decomposition temperature no data available
r)
Viscosity no data available
s)
Explosive properties no data available
t)
Oxidizing properties no data available
Other
safety information no data available
10.
STABILITY AND REACTIVITY
Reactivity
no data available
Chemical
stability no data available
Possibility
of hazardous reactions no data available
Conditions
to avoid Exposure to moisture.
Incompatible
materials Strong oxidizing agents, Strong
acids
Hazardous
decomposition products Other decomposition
products - no data available
11.
TOXICOLOGICAL INFORMATION
Information
on toxicological effects
Acute
toxicity no data available
Skin
corrosion/irritation no data available
Serious
eye damage/eye irritation no data available
Respiratory
or skin sensitization no data available
Germ
cell mutagenicity no data available
Carcinogenicity
IARC: No component of this product present
at levels greater than or equal to 0.1% is identified as
probable,
possible or confirmed human carcinogen by IARC.
Reproductive
toxicity no data available
Specific
target organ toxicity - single exposure no
data available
Specific
target organ toxicity - repeated exposure no
data available
Aspiration
hazard no data available
Potential
health effects Inhalation May be harmful if
inhaled. May cause respiratory tract irritation.
Ingestion
Toxic if swallowed.
Skin
May be harmful if absorbed through skin.
May cause skin irritation.
Eyes
May cause eye irritation.
Signs
and Symptoms of Exposure
To
the best of our knowledge, the chemical, physical, and toxicological properties
have not been thoroughly
investigated.
Additional
Information RTECS: Not available
12.
ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence
and degradability no data available
Bioaccumulative
potential no data available
Mobility
in soil no data available
Results
of PBT and vPvB assessment no data
available
Other
adverse effects Very toxic to aquatic life.
13.
DISPOSAL CONSIDERATIONS
Waste
treatment methods
Product
Offer surplus and non-recyclable solutions
to a licensed disposal company. Contact a licensed professional
waste
disposal service to dispose of this material. Dissolve or mix the material with
a combustible solvent
and
burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated
packaging Dispose of as unused product.
14.
TRANSPORT INFORMATION
UN
number
ADR/RID:
2811 IMDG: 2811 IATA: 2811
UN
proper shipping name
ADR/RID:
TOXIC SOLID, ORGANIC, N.O.S. (1,10-Phenanthroline chloride monohydrate)
IMDG:
TOXIC SOLID, ORGANIC, N.O.S. (1,10-Phenanthroline chloride monohydrate)
IATA:
Toxic solid, organic, n.o.s. (1,10-Phenanthroline chloride monohydrate)
Transport
hazard class(es)
ADR/RID:
6.1 IMDG: 6.1 IATA: 6.1
Packaging
group
ADR/RID:
III IMDG: III IATA: III
Environmental
hazards
ADR/RID:
no IMDG Marine pollutant: no IATA: no
Special
precautions for user
no
data available
15.
REGULATORY INFORMATION
This
safety datasheet complies with the requirements of Regulation (EC) No.
1907/2006.
Safety,
health and environmental regulations/legislation specific for the substance or
mixture
no
data available
Chemical
Safety Assessment
no
data available
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